Has cyanide been used in chemical warfare?
Cyanide is a rapidly lethal agent when used in enclosed spaces where high concentrations can be achieved easily. Cyanide was first used as a chemical weapon in the form of gaseous HCN in World War I. Starting in 1915, the French military used approximately 4000 tons of cyanide, without notable success.
What is hydrogen cyanide commonly used for?
Hydrogen cyanide may be used in the workplace for fumigation, electroplating, mining, chemical synthesis, and the production of synthetic fibers, plastics, dyes, and pesticides.
What chemicals make up cyanide gas?
A cyanide is a chemical compound that contains the group C≡N. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom. In inorganic cyanides, the cyanide group is present as the anion CN−. Soluble salts such as sodium cyanide and potassium cyanide are highly toxic.
When was hydrogen cyanide used?
It was discovered in 1782 by a Swedish chemist, Carl Wilhelm Scheele, who prepared it from the pigment Prussian blue. Hydrogen cyanide and its compounds are used for many chemical processes, including fumigation, the case hardening of iron and steel, electroplating, and the concentration of ores.
How much hydrogen cyanide is in a cigarette?
Cigarette smoke can contain high levels of carbon monoxide. Hydrogen cyanide was used to kill people in the gas chambers. It can be found in cigarette smoke. Nicotine is a poison used in pesticides and is the addictive element in cigarettes.
Is cyanide gas flammable?
Sodium cyanide releases highly flammable and toxic hydrogen cyanide gas on contact with acids or water. Fire will produce irritating, corrosive, and/or toxic gases.
Is hydrogen cyanide gas or liquid?
Agent Characteristics. APPEARANCE: Colorless or pale blue liquid below 78°F (25.6°C), colorless gas above 78°F (25.6°C). DESCRIPTION: Hydrogen cyanide (AC) is a systemic chemical asphyxiant.
At what pH does cyanide gas off?
At a pH of 11, over 99% of the cyanide remains in solution as CN-, while at pH 7, over 99% of the cyanide will exist as HCN. At a pH of 9.3 – 9.5, CN– and HCN are in equilibrium, with equal amounts of each present.
What creates hydrogen cyanide?
Hydrogen cyanide (CN), the gaseous form of cyanide, is generated by the combustion of nitrogen- and carbon-containing substances such as wool, silk, cotton, and paper as well as synthetic substances such as plastic and other polymers.
What are the 4 000 chemicals in cigarettes?
Some of the chemicals found in tobacco smoke include:
- Nicotine (the addictive drug that produces the effects in the brain that people are looking for)
- Hydrogen cyanide.
- Formaldehyde.
- Lead.
- Arsenic.
- Ammonia.
- Radioactive elements, such as polonium-210 (see below)
- Benzene.
Where is cyanide found?
Cyanides can be produced by certain bacteria, fungi and algae. Cyanides are also found in cigarette smoke, in vehicle exhaust, and in foods such as spinach, bamboo shoots, almonds, lima beans, fruit pits and tapioca.
Can I smell cyanide?
Cyanide sometimes is described as having a “bitter almond” smell, but it does not always give off an odor, and not everyone can detect this odor. Cyanide is also known by the military designations AC (for hydrogen cyanide) and CK (for cyanogen chloride).
When was hydrogen cyanide used as a war gas?
There are also reports of hydrogen cyanide being used as a war gas during the Iran–Iraq war in the 1980s (Lang et al., 1986; Heylin, 1988). However, because hydrogen cyanide can be detoxified rapidly by humans and because it is very volatile, massive amounts of the gas are needed for it to be effective as a chemical warfare agent.
What are the uses of cyanide in manufacturing?
In manufacturing, cyanide is used to make paper, textiles, and plastics. It is present in the chemicals used to develop photographs. Cyanide salts are used in metallurgy for electroplating, metal cleaning, and removing gold from its ore. Cyanide gas is used to exterminate pests and vermin in ships and buildings.
What kind of chemical compound is hydrogen cyanide?
HCN is produced on an industrial scale and is a highly valued precursor to many chemical compounds ranging from polymers to pharmaceuticals. Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen.
What is the odor of hydrocyanic acid gas?
Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide is a clear colorless aqueous solution of a gas. Has a faint odor of almonds. Can evolve hydrogen cyanide gas, which is (barely) lighter than air. Flame can flash back to the source of a gas leak very easily.