What are the chemicals used in boiler water treatment?
The most common alkaline solutions for boiler water include sodium hydroxide and potassium hydroxide. You can typically purchase these products with a 25 percent concentration or a 50 percent concentration.
What is phosphate test in boiler water?
A boiler phosphate test kit is commonly used to monitor proper phosphate residuals in the boiler water, hot water, or steam boiler. A typical phosphate residual in boiler water is between 10 to 20 ppm of phosphate or 7 ppm of phosphate per 1 ppm of hardness.
What chemical is added to control hardness in a boiler?
Phosphates. Phosphate treatment programs precipitate calcium and magnesium hardness from boiler feedwater in the form of hydroxyapatite and serpentine. These compounds form sludge, which, when properly conditioned with polymers, is removed from the boiler via blowdown.
What chemical would be used to control alkalinity in a boiler?
In an emergency, increase the blow down rate if necessary to bring boiler water alkalinity under control. Sodium hydroxide is the preferred approach, as the break down components does not form carbon dioxide. Carbon dioxide will carry off the steam and form carbonic acid in the condensate return lines.
Why trisodium phosphate is used in boiler?
Trisodium phosphate is the most common compound for lower pressure boilers. Phosphates also scavenge (or remove) any remaining oxygen and create a pH buffer to minimize corrosion potential. Compounds that remain in solution can then be eliminated by blowdown.
What is phosphate hideout in boiler?
Phosphate hideout is characterized by the retention of phosphate in the boiler during conditions of high pressure and the subsequent release of phosphate when the pressure is reduced. The condition is most often reported in high-pressure units, e.g., 2,500 psi (17.24 MPa).
What causes high TDS in boilers?
As water is boiled within the boiler and steam is produced, then the solids remain in the water and concentrate. Thus, over time the level of total dissolved solids (TDS) increases. Further evaporation causes these dissolved solids to come out of solution, and to produce suspended solids (sludge).
What is the function of hydrazine in boiler water?
2.2 Corrosion-control effects of hydrazine Oxygen dissolved in water causes corrosion. Because hydrazine removes this oxygen via the reaction N2H4 + O2 → N2 + 2H2O, it is useful in preventing corrosion. It decomposes at a temperature of 200°C or more to form ammonia (3N2H4 → 4NH3 + N2) , which acts as a pH adjuster.
What does phosphate do to boiler water?
Phosphate compounds are common additives for boiler water treatment. Phosphate compounds react with any remaining hard water compounds to create a soft sludge that is eliminated through blowdown. Phosphates also scavenge (or remove) any remaining oxygen and create a pH buffer to minimize corrosion potential.
Why ammonia and hydrazine is added in boiler feed water?
How is trisodium phosphate used in high pressure boilers?
The water used in high pressure steam plants is Inferred pH in Steam Plant Water Chemistry Monitoring conductivity in phosphate treated boilers. one mole of trisodium phosphate will increase boiler water pH Correcting the dosage of phosphate if the Although high pressure boilers and the
How is pH controlled in a high pressure boiler?
HIGH PRESSURE BOILER Control of pH comes from hydrolysis of trisodium phosphate in water Na 3 PO DSS Boiler Water Treatment Technologyh1.ppt Boiler Chemicals 101 by the heat and pressure of the boilers. di- or trisodium phosphate and sodium polyphosphate can be added to treat boiler feedwater.
What is the molecular weight of trisodium phosphate?
Trisodium phosphate PubChem CID 24243 Molecular Weight 163.941 Component Compounds CID 5360545 (Sodium) CID 1004 (Phosphori Date s Modify 2021-07-10 Create 2005-08-08
How is alkalinity used in boiler water treatment?
– Excess hydrate alkalinity led to metal damage in the form of caustic embrittlement (cracking) or gouging. • New boiler water treatment was developed using the alkalinity derived from phosphate alone, eliminating sodium hydroxide. – The sodium to phosphate ratio determines the pH of the water (3:1)